Spray a deep 12 inch skillet with cooking spray. Brown chops evenly on both sides. Remove from skillet and set aside.
Place rice over bottom of skillet. Arrange chops over rice. Top each chop with one onion, tomato and pepper slice. Sprinkle with salt and pepper. Pour tomato juice over chops and cover.
Simmer for 45 minutes or until chops are tender. Makes 6 servings. Enjoy!